*
 

iForest - Biogeosciences and Forestry

*

Estimation of total extractive content of wood from planted and native forests by near infrared spectroscopy

Luana Teixeira Mancini, Fernanda Maria Guedes Ramalho, Paulo Fernando Trugilho, Paulo Ricardo Gherardi Hein   

iForest - Biogeosciences and Forestry, Volume 14, Issue 1, Pages 18-25 (2021)
doi: https://doi.org/10.3832/ifor3472-013
Published: Jan 09, 2021 - Copyright © 2021 SISEF

Research Articles


The aim of this study was to evaluate the performance of multivariate models using Near infrared (NIR) spectra for predicting total extractives content of solid and powdered wood of planted and native species from tropical savanna. NIR spectra were recorded on the milled wood and radial surface of solid wood specimens of Cedrela sp., Jacaranda sp., Apuleia sp., Aspidosperma sp. and clones of Eucalyptus hybrids via an integrating sphere and fiber optics probe. NIR spectral signatures were evaluated by Principal Component Analysis (PCA) and then associated to the total extractive content quantified by extraction in toluene/ethanol (2:1) solutions, pure ethanol and hot water by Partial Least Squares (PLS) regressions. PCA revealed that NIR spectra measured in solid wood by integrating sphere gave a better discrimination of wood species. A global PLS model was developed based on NIR obtained by integrating sphere with satisfactory estimations both for solid wood (R²cv= 0.87, RMSECV= 1.08%) and wood powder (R²cv= 0.85, RMSECV= 1.19%). An independent test-set validation was performed with 25% of the samples and yielded R²p= 0.93 and RMSEP= 0.95% (for solid wood) and R²p= 0.87 and RMSEP= 1.40% (for wood powder). Both models can be applied for rapid screenings, though models developed from NIR spectra by integrating sphere on solid wood are considered more suitable for rapid predictions of extractive content in unknown wood specimens.

  Keywords


Lumber, Multivariate Analysis, Non-destructive Testing, Test Set Validation, Wood Chemistry

Authors’ address

(1)

Corresponding author

 
Paulo Ricardo Gherardi Hein
fernandaguedesrm@hotmail.com

Citation

Teixeira Mancini L, Guedes Ramalho FM, Trugilho PF, Gherardi Hein PR (2021). Estimation of total extractive content of wood from planted and native forests by near infrared spectroscopy. iForest 14: 18-25. - doi: 10.3832/ifor3472-013

Academic Editor

Giacomo Goli

Paper history

Received: Apr 15, 2020
Accepted: Nov 06, 2020

First online: Jan 09, 2021
Publication Date: Feb 28, 2021
Publication Time: 2.13 months

Breakdown by View Type

(Waiting for server response...)

Article Usage

Total Article Views: 25920
(from publication date up to now)

Breakdown by View Type
HTML Page Views: 22568
Abstract Page Views: 1391
PDF Downloads: 1586
Citation/Reference Downloads: 8
XML Downloads: 367

Web Metrics
Days since publication: 1165
Overall contacts: 25920
Avg. contacts per week: 155.74

Article Citations

Article citations are based on data periodically collected from the Clarivate Web of Science web site
(last update: Feb 2023)

(No citations were found up to date. Please come back later)


 

Publication Metrics

by Dimensions ©

Articles citing this article

List of the papers citing this article based on CrossRef Cited-by.

 
(1)
ABTN (2010)
NBR 14853: determinação do material solúvel em etanol-tolueno e em diclorometano e acetona [Determination of the material soluble in ethanol-toluene and in dichloromethane and acetone]. Brazilian Association of Technical Standards - ABTN, Rio de Janeiro, Brazil, pp. 3. [in Portuguese]
Gscholar
(2)
Browning BL (1963)
The Chemistry of wood. Wiley, New York, USA, pp. 689.
Gscholar
(3)
Cetera P, Russo D, Milella L, Todaro L (2019)
Thermo-treatment affects Quercus cerris L. wood properties and the antioxidant activity and chemical composition of its by-product extracts. Industrial Crops and Products 130: 380-388.
CrossRef | Gscholar
(4)
Foelkel CEB (1977)
Estrutura da madeira [Timber structure]. Cenibra, Belo Oriente, Brazil, pp. 84. [in Portuguese]
Gscholar
(5)
Gierlinger N, Schwanninger M, Hinterstoisser B, Wimmer R (2002)
Rapid determination of heartwood extractives in Larix sp. by means of Fourier transform near infrared spectroscopy. Journal of Near Infrared Spectroscopy 10: 203-214.
CrossRef | Gscholar
(6)
He W, Hu H (2013)
Rapid prediction of different wood species extractives and lignin content using Near Infrared Spectroscopy. Journal of Wood Chemistry and Technology 33: 52-64.
CrossRef | Gscholar
(7)
Hsing TY, Paula NF, Paula RC (2016)
Características dendrométricas, químicas e densidade básica da madeira de híbridos de Eucalyptus grandis × Eucalyptus urophylla [Dendrometric, chemical characteristics and basic density of wood from Eucalyptus grandis × Eucalyptus urophylla]. Ciência Florestal 26: 273-283. [in Portuguese]
CrossRef | Gscholar
(8)
Li Y, Altaner C (2019)
Calibration of near infrared spectroscopy (NIRS) data of three Eucalyptus species with extractive contents determined by ASE extraction for rapid identification of species and high extractive contents. Holzforschung 73 (6): 537-545.
CrossRef | Gscholar
(9)
Li Y, Altaner C (2018)
Predicting extractives content of Eucalyptus bosistoana F. Muell. Heartwood from stem cores by near infrared spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 198: 78-87.
CrossRef | Gscholar
(10)
Li Y, Deng X, Zhang Y, Huang Y, Wang C, Xiang W, Xiao F, Wei X (2019)
Chemical characteristics of heartwood and sapwood of red-heart Chinese fir (Cunninghamia lanceolata). Forest Products Journal 69 (2): 103-109.
CrossRef | Gscholar
(11)
Lovaglio T, D’Auria M, Rita A, Todaro L (2017)
Compositions of compounds extracted from thermo-treated wood using solvents of different polarities. iForest - Biogeosciences and Forestry 10 (5): 824-828.
CrossRef | Gscholar
(12)
Nunes CA, Freitas MP, Pinheiro ACM, Bastos SC (2012)
Chemoface: a novel free user-friendly interface for chemometrics. Journal of the Brazilian Chemical Society 23: 2003-2010.
CrossRef | Gscholar
(13)
Oliveira JTS, Della Lucia RM (1994)
Teores de extrativos de 27 espécies de madeiras nativas do Brasil ou aqui introduzidas [Extractive content of 27 species of native wood from Brazil or introduced here]. Boletim Técnico SIF 9, Viçosa, Brazil, pp. 5. [in Portuguese]
Gscholar
(14)
Pereira H, Graça J, Rodrigues JC (2003)
Wood chemistry in relation to quality. In: “Wood Quality and its Biological Basis” (Barnett JR, Jeronimidis G eds). Oxônia, Blackwell, pp. 226.
Gscholar
(15)
Pereira BLC, Oliveira AC, Carvalho AMML, Carneiro ACO, Santos LC, Vital BR (2012)
Quality of wood and charcoal from Eucalyptus clones for ironmaster use. International Journal of Forestry Research 2012: 1-8.
CrossRef | Gscholar
(16)
Pettersen RC (1984)
The chemical composition of wood. In: “The chemistry of solid wood”, vol. 207 (Rowell R ed). American Chemical Society, Washington, DC, USA, pp. 54-126.
CrossRef | Gscholar
(17)
Poke FS, Wright JK, Raymond CA (2004)
Predicting extractives and lignin contents in Eucalyptus globulus using near infrared reflectance analysis. Journal of Wood Chemistry and Technology 24: 55-67.
CrossRef | Gscholar
(18)
Poke FS, Raymond CA (2006)
Predicting extractives, lignin, and cellulose contents using near infrared spectroscopy on solid wood in Eucalyptus globulus. Journal of Wood Chemistry and Technology 26: 187-199.
CrossRef | Gscholar
(19)
Ramalho FMG, Hein PRG, Andrade JM, Napoli A (2017)
Potential of near infrared spectroscopy for distinguishing charcoal produced from planted and native wood for energy purpose. Energy Fuels 31: 1593-1599.
CrossRef | Gscholar
(20)
Santos SAO, Vilela C, Domingues RMA, Oliveira CSD, Villaverde JJ, Freire CSR, Neto CP, Silvestre AJD (2017)
Secondary metabolites from Eucalyptus grandis wood cultivated in Portugal, Brazil and South Africa. Industrial Crops and Products 95: 357-364.
CrossRef | Gscholar
(21)
Shebani AN, Reenem AJ, Meincken M (2008)
The effect of wood extractives on the thermal stability of different wood species. Thermochimica Acta 471: 43-50.
CrossRef | Gscholar
(22)
Silva AR, Pastore TCM, Braga JWB, Davrieux F, Okino EYA, Coradin VTR, Camargos JAA, Prado AGS (2013)
Assessment of total phenols and extractives of mahogany wood by near infrared spectroscopy (NIRS). Holzforschung 67: 1-8.
CrossRef | Gscholar
(23)
Timm NH (2002)
Applied multivariate analysis. Springer Texts in Statistics, Springer, New York, USA, pp. 693.
Gscholar
(24)
Trugilho PF, Lima JT, Mendes LM (1996)
Influência da idade nas características físico-químicas e anatômicas da madeira de Eucalypus saligna. [Influence of age on the physicochemical and anatomical characteristics of Eucalyptus saligna wood]. Cerne 2: 15. [in Portuguese]
Gscholar
(25)
Tsuchikawa S, Kobori HA (2015)
Review of recent application of near infrared spectroscopy to wood science and technology. Journal of Wood Science 61: 213-220.
CrossRef | Gscholar
(26)
Tsuchikawa S, Schwanninger MA (2013)
Review of recent near-infrared research for wood and paper (Part 2). Applied Spectroscopy Reviews 48: 560-587.
CrossRef | Gscholar
(27)
Uner B, Karaman I, Tanreverdi H, Ozdemir D (2011)
Determination of lignin and extractive content of Turkish Pine (Pinus brutia Ten.) trees using near infrared spectroscopy and multivariate calibration. Wood Science and Technology 45: 121-134.
CrossRef | Gscholar
(28)
Várhegyi G, Gronli MG, Di Blasi C (2004)
Effects of sample origin, extraction, and hot-water washing on the devolatilization kinetics of chestnut wood. Industrial and Engineering Chemistry Research 43: 2356-2367.
CrossRef | Gscholar
(29)
Zobel BJ, Van Buijtenen JP (1989)
Wood variation: its causes and control. Springer Verlag, Berlin, Germany, pp. 363.
Gscholar
 

This website uses cookies to ensure you get the best experience on our website. More info